If you were using FCKeditor 2.x and now want to move to the new product line, CKEditor 3.x, you will quickly find that along with a complete code rewrite some of the configuration options have changed their names.
If you want to customize your CKEditor installation in the same way as you did with FCKeditor, use the Configuration Settings Mapping Between FCKeditor and CKEditor article to find a complete list of settings that are equivalent to what you are used to.